# 2010 Vancouver
Silane method is a preferred technique of crosslinking polyethylene to modify its properties. Higher ESCR as well as thermal resistance should no longer be demonstrated. Conventional HDPE, LLDPE or LDPE are known to offer different sensitivity to level of silane, curing time and temperature; rate of crosslinking and gel content may differ as well. Many parameters of the base polymer molecular structure have to be taken into account when developing a PEXb compound like vinyl insaturation, vinylidene groups, tertiary carbons, (short and long chain) branching number and distribution, polydispersity index, molecular weight, antiThe literature shows that HDPE usually exhibits lower silane grafting efficiency vs LLDPE or LDPE less increase in zero shear viscosity longer time of crosslinking These observations are constraints for new applications although products offered today show a broad range of characteristics in terms of density (product stiffness) and Melt Index (processability). Base resins can be mapped the same way although the molecular structure may be altered by the reaction pathways with peroxide and silane. 2nd generation metallocene-catalysed HDPE or MDPE offer an alternative to conventional base resins for PEXb as their unique molecular structure will react a different way during the silane grafting and the crosslinking processes allowing to target never achieved before performance in terms of processing behaviour and mechanical properties. High Melt Index 2nd generation metallocene-catalysed HDPE or MDPE offer indeed a unique alternative to Ziegler-Natta equivalent resins thanks to their more favourable molecular structure.