Additives
Plastic Pipes Conference Association # 2006 Washington DC
Fumire
The level of gelation is a very important parameter in moulded PVC items since it will determine in a significant extent the mechanical properties of the item.
Several methods have been developed already but none was widely used in processing plants except the Methylene Chloride test (MCT) which gives a pass/fail answer and is dependent from the operator's skill.
The need for an accurate and reliable measurement of the gelation has been stressed within the PVC industry since a few years and is assessed in the preparation of an ISO standard using a Differential Scanning Calorimetry (DSC) measurement (ISO/TC138/SC5/WG2).
The DSC spectrum can present variations in the shape of the endotherms and some authors consider that the additives present in the formulation can have a significant influence on the crystallisation and hence on this spectrum. The main target of this work was to assess the robustness of this method by checking the influence of some standard additives of a PVC formulation.
Related papers
Author(s) : A. Marangoni
The quality of infrastructures is a key driver for maximizing the performance of the utilities networks and minimizing the environmental impacts associated with their operation. The water and sewer pipes are key network elements to guarantee a satisfactory service to the citizens. Their end-of-life management is an...
Author(s) : Saleem Shakir
Unplasticized formulations based on Poly(Vinyl Chloride) (PVC) and Chlorinated Poly(Vinyl Chloride) (CPVC) resins offer technical solution to pressure piping systems that find extensive use in residential and industrial applications. Building upon the desirable properties of the vinyl monomer, the chlorine content of...
Author(s) : James F. Mason, Akshay Ponda, Hermann van Laak, Buc Slay
The effects of liquid hydrocarbons on long term strength of pipe grade thermoplastic resins is an important consideration when designing pressure pipe for use in the oil and gas industry. There is an extensive body of work going back several decades descri bing these effects for pipe grade polyethylenes, and all...
Author(s) : Antonio Rodolfo Jr., Vanderley M. John
Unplasticised (U-PVC) and modified (M-PVC) pipes used in irrigation and infrastructure applications, outside diameter 326 mm, were evaluated according to various fracture mechanics methodologies, including fracture toughness (stress intensity factor KC and energy release rate GC, both at fracture), essential work of...
Author(s) : C. Losher and P.V. Mercea
In the framework of the German Environmental Agency (UBA) requirements of plastic articles in contact with drinking water (KTW-BWGL-guideline), the compliance is verified by comparing so-called “expected concentrations at tap”, C tap , of substances contained in the plastics with specific limits in drinking water...
Author(s) : Sylvie Famelart, Vincent. Stone
In order to deliver to the market reliable and consistent information about PVC and the different PVC pipe solutions, a Training Package was developed a few years ago. The package was made up of a set of standalone PowerPoint slides, providing information on PVC-U and PVC-C pipe systems. Information on both general...
Author(s) : Argnani Claudio, Ing. Gianpaolo Contarini
...Clogging of the pipes can be experienced in sewer systems after a short period of service, due to the intrusion of roots from plants and trees. Plants, and in particular their roots, are attracted by the water flowing inside the pipes. These roots will strain the connections between pipes, in particular the sockets...
Author(s) : Ignacio Muñoz
“Food is the new oil and gas” is a rather bold statement, but everyday more and more people are concerned about food scarcity. Bringing irrigation to not productive lands will change the lives of the community and if it can be done with a cost effective and the most ecofriendly solution, even better. This case study...
Author(s) : Guido Quesada
An important breakthrough for belled PVC pipe was made around 2006, when the first versions an integral joint restraint were released, after about two years in development. This type of restraint comprises a casing, usually made of metal such as ductile iron or stainless steel, a rubber seal, and a “C” grip ring,...
Author(s) : Andreas Frank, Mario Messiha, Günter Dreiling, Norbert Schuler, Jens-Martin Storheil, Erwin Mayrbäurl, Stuart Ramella, Frank Krause, Rudi Berning, Philippe Gabriëls, Alpay Aydemir, Thomas Koch, Florian Arbeiter, Gerald Pinter
The Cyclic Cracked Round Bar (CRB) Test has been applied to study the slow crack growth (SCG) resistance of virgin, recycled, and reprocessed PVC-U. This fracture mechanical test allows a quick ranking of the SCG resistance of PVC-U. A clear correlation between the K-value and the SCG resistance has been elaborated....
Author(s) : Dr. Stefan Fokken
NGO pressure and end of life disposal of PVC articles in the EU over 30 years ago, triggered intense discussion about the sustainable use of PVC and its additives. Stabiliser producers and downstream users of PVC stabiliser compounds base upon Lead and Cadmium based stabilisers have developed solutions ultimately...
Author(s) : E. Boccaleri, L. Palin, G. Rombolà, M. Milanesio
In the last decades, research on nanostructured materials as additives for plastics involved several polymeric matrices, but only limited studies and publications involve PVC. In this work, the context of rigid application of PVC (U-PVC) for pipes application was targeted, in order to test and evaluate the structural...
Author(s) : Steven Folkman
A recent survey again confirms that PVC pipe has the lowest break rate when compared with break rates of ductile and cast iron, asbestos cement, steel, and concrete pipe. Other results of interest to water utilities and engineers are discussed. During 2017, Utah State University conducted a survey of utilities across...
Author(s) : Ignacio Muñoz
During the last years PVC-O has become a popular product in pipe business due to the huge improvements of mechanical properties of PVC after orientation. At the same time, CPVC has become an important choice for hot water conduits in in-house applications. Molecor has started a research program to evaluate the...
Author(s) : G.M. Quesada, K.H. Steinbruck
The benefits of molecularly oriented PVC pipe (PVC-O) are well known and documented. Numerous studies covering improved pipe impact, toughness, hydraulics, and life cycle have been published. There is less information about PVC-O pipe under pipeline hydraulic forces. The objective of this paper is to identify design...
Author(s) : Liang Yu, Akshay Ponda, Dane Chang
Following the development of US shale oil and gas production since 2007, the demand for thermoplastic pipes with better corrosion resistance, and lower installation and operation cost than carbon steel pipe, has been growing significantly. Nylon 12 has been qualified for hydrocarbon transportation in offshore flexible...
Author(s) : Amanda Hawkins, Jason Lawrence, Xiangli Meng
High Density Polyethylene pipes are used in various applications due to the material’s superior chemical resistance, pressure capability, and ductility. For the material to perform at the optimal design criteria, the connections and fabrications must be fused using repeatable procedures that specify proper fusion...
Author(s) : Dominique GUEUGNAUT, Adil BOUJLAL, Aymeric LOPITAUX, Bertrand SEVRE
A special concept has been developed by GRTgaz Research and Innovation Center for Energy (RICE) for temperature mapping at the interface of an electrowelded assembly.The technical solution consists of a tubular piece in place of the real PE pipe, made of a non-weldable polymer with thermal parameters close to those of...
Author(s) : Joaquín Lahoz Castillo
Irrigation networks in Spain extensively make use of plastic pressure pipes systems. Some recent failures focus the attention on Rapid Crack Propagation phenomena. Larger high-pressure PVC-u pipes are involved in most incidences detected. The level of gelation of those pipes were measured per EN-ISO 1452-2 test...
Author(s) : Richard St-Aubin, Dr. Thomas O’Rourke, Dr. Brad Wham, Blake Berger
Molecularly oriented polyvinyl chloride (PVC-O) pipe has been found to withstand large ground deformation during seismic events without damage. The properties of PVC-O pipe that support this performance have been investigated in a multi-year testing program undertaken at the Geotechnical Lifelines Large Scale Testing...
Members of the Association
